These guides are a compiled list from the Heroes-Wow forums, some minor changes have been made where needed. 

Starting Guide:

As you start you will spawn into the leveling Road. Your first point of call is the NPC known as Heroes-Wow Start Vendor, This is where you will be able to obtain your first set of items for leveling, including weapons and rings. 

As a fresh 225, the best way to gear up is to visit the T6 Vendor, at the crossroads. Alternativley NPCs can be found throughout the leveling road which will give you the gear set, of your choice

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